Thermodynamics and Kinetics of Materials detail syllabus for Materials Science And Engineering (Material Science), 2017 regulation is taken from Anna University official website and presented for students of Anna University. The details of the course are: course code (ML8302), Category (PC), Contact Periods/week (5), Teaching hours/week (3), Practical Hours/week (2). The total course credits are given in combined syllabus.
For all other material science 3rd sem syllabus for be 2017 regulation anna univ you can visit Material Science 3rd Sem syllabus for BE 2017 regulation Anna Univ Subjects. The detail syllabus for thermodynamics and kinetics of materials is as follows.”
Course Objective:
- To introduce the basic knowledge of thermodynamics required for understanding various alloy systems, phase transformations and interpreting properties
Unit I
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Unit II
Internal Energy and Entropy
First law of Thermodynamics: Relation between Heat and work, Internal energy, Enthalpy. The Second law of thermodynamics: Spontaneous process, Degree of measure of reversibility and irreversibility, Maximum work, criteria of equilibrium. Combined statement of first and second laws on thermodynamics. Statistical interpretation of entropy: Concept of microstate, most probable microstate, Thermal equilibrium, Boltzman equation
Unit III
Auxilary Functions and Thermodynamic Potentials
Auxiliary functions: Helmholtz, Gibbs free energy, Maxwells equation, Gibbs-Helmholtz equations. Concept of Third law, temperature dependence of entropy, statistical interpretation of entropy, Deby and Einstein concept of heat capacity, relation between Cp and Cv, Consequences of third law. Zeroth law of thermodynamics and its applications. Thermodynamic potentials: Fugacity, Activity and Equilibrium constant. Clausius – Clayperon equation. Le Chateliers principle, Vant Hoffs equation.
Unit IV
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Unit V
Thermodynamics of Reactions
Thermodynamics of electrochemical cells, solid electrolytes. Basic – Pourbaix diagrams. Thermodynamics of Surfaces: Adsorption isotherms, Effect of surface energy on pressure and phase transformation temperature. Thermodynamics of Defects in solids: Point defects, vacancies and interstitials in solid metals.
Course Outcome:
- To remember the fundamental concepts of thermodynamics
- Able to understand first and second laws of thermodynamics and solve related problems.
- Able to apply the basic laws and derive auxiliary functions and chemical potential.
- Able to understand the thermodynamics of solution in phase diagrams
- Able to understand and apply to solve problems related to thermodynamics of reactions.
Text Books:
- Boris.S.Bokstein, Mikhail I. Mendelev, David J. Srolovitz, “Thermodynamics and Kinetics in Materials science”, Oxford University Press 2005.
- David R Gaskell, Introduction to the Thermodynamics of materials, Taylor and Francis, Fifth edition, 2008.
References:
- Ahindra Ghosh, T”extbook of Materials and Metallurgical Thermodynamics”, Prentice hall of India, 2003.
- DeHoff R T, “Thermodynamics in Materials Science”, McGraw Hill, New York 1993.
- David V Ragone, Thermodynamics of Materials – Volume-1, John Wiley and Sons, Inc. 1995.
- Darken LS and Gurry R W ,Physical Chemistry of Metals, McGraw Hill, 1987.
- J J Moore, Chemical Metallurgy, Butterworth-Heinemann Ltd, 1990.
- Prasad, Krishna Kant, Ray, H. S. and Abraham, K. P., Chemical and Metallurgical Thermodynamics, New Age International, 2006
- Peter Atkins, Julio de Paula, Physical Chemistry Volume 1: Thermodynamics and Kinetics, W. H. Freeman and Company, 2010
- Swalin R A, Thermodynamics of solids, John Wiley Sons Inc, third edition, 1966.
- Thomas Engel, Philip Reid, “Thermodynamics, Statistical Thermodynamics and Kinetics”, Pearson Education (LPE) 2007.
- Upadhyaya, G. S. and Dube, R. K., Problems in Metallurgical Thermodynamics and Kinetics, Pergamon Press, London, 1977.
For detail syllabus of all other subjects of BE Material Science, 2017 regulation do visit Material Science 3rd Sem syllabus for 2017 Regulation.
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