Chemical Reaction Kinetics detailed Syllabus for Chemical Engineering (CH), K scheme PDF has been taken from the MSBTE official website and presented for the diploma students. For Subject Code, Subject Name, Lectures, Tutorial, Practical/Drawing, Credits, Theory (Max & Min) Marks, Practical (Max & Min) Marks, Total Marks, and other information, do visit full semester subjects post given below.
For all other MSBTE Chemical Engineering 4th Sem K Scheme Syllabus PDF, do visit MSBTE Chemical Engineering 4th Sem K Scheme Syllabus PDF Subjects. The detailed Syllabus for chemical reaction kinetics is as follows.
Rationale
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Course Outcomes:
Students will be able to achieve & demonstrate the following COs on completion of course based learning
- Perform kinetics of different chemical reactions.
- Use appropriate catalyst for enhancing rate of reaction.
- Identify the order of reactions based on interpretation of batch reactor data.
- Calculate the size of reactor by using the knowledge of design reactor equations.
- Identify suitable reactor for best conversion of reactants.
Unit I
Kinetics of Homogeneous Reactions 1.1 Concept of chemical kinetics, parameters affecting the rate of reaction. 1.2 Types of Reaction (Definition and examples): a. Homogenous and Heterogeneous reactions b. Catalytic non catalytic reactions c. Molecularity of reaction d. Exothermic and endothermic reactions e. Order of reaction f. Reversible and irreversible reactions g. Elementary and non-elementary reaction. h. Chain and non-chain reaction. 1.3 Reaction rate, rate equation, rate constant, units of rate constant, concentration dependent term of rate equation. 1.4 Kinetics of non-elementary reactions (homogeneous reaction) 1.5 Activation energy and its significance and numericals. 1.6 Derive temperature dependency of rate constant from: a. Arrhenuis law b. Transition state theory c. Collision Theory d. Compare Arrhenuis, Transition state theory and Collision Theory (Numericals)
Suggested Learning Pedagogie
Lecture Usi Chalk-Boar Presentation Video Demonstrati
Unit II
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Unit III
Interpretation of Batch Reactor Data 3.1 Concept of constant volume batch reactor and variable volume batch reactor 3.2 Constant Volume Batch Reactor: Relation between concentration and conversion for constant volume system 3.3 Methods of analysis of kinetic data/rate data: Integral method, differential method, half-life method, Ostwald isolation method and initial rate method 3.4 General procedure for integral method for analysis of kinetic data for constant volume reactor a. Integrated rate expression for Irreversible unimolecular type first order reactions and its characteristics b. Integrated rate expression for irreversible bimolecular type second order reactions (2A → Product and A+B→ Product) and its characteristics c. Integrated rate expression for zero order reaction and its characteristics d. Integrated rate expression for nth order reaction (Numericals) 3.5 Variable Volume Batch Reactor to Analyse the Kinetic Data/Rate Data: a. Concept of εA b. Integrated rate expression for irreversible unimolecular type first order reaction c. Integrated rate expression for irreversible bimolecular type second order reactions (2A → Product) d. Integrated rate expression for zero order reaction (Numericals)
Suggested Learning Pedagogie
Lecture Usi Chalk-Boar Presentation Video Demonstrati
Unit IV
Reactor Design 4.1 Classification of Reactors (diagram, brief description and applications): Batch, semi-batch, continuous stirred tank reactor, tubular/plug flow, fixed bed and fluidised bed reactor 4.2 Performance/design equation for ideal batch reactor for constant and variable volume system with their graphical representation. (Numericals) 4.3 Concept of space time, space velocity, holding time for flow reactors. (Numericals) 4.4 Performance/design equation for steady state continuous stirrer tank reactor (CSTR) for constant and variable volume system with their graphical representation. (Numericals) 4.5 Performance/design equation for steady state Plug flow reactor (PFR) for Constant and variable volume system with their graphical representation. (numericals)
Suggested Learning Pedagogie
Lecture Usi Chalk-Boar Presentation Video Demonstrati
Unit V
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List of Experiments:
- * Determination of activation energy of saponification of ethyl acetate and sodium hydroxide at various temperatures. 4 C
- *Determination of the activation energy of the reaction by hydrolysis of methyl acetate at various temperatures. 4 C
- *Determination of Arrhenius rate constants for acidic hydrolysis of methyl acetate at various temperatures. 4 C
- *Determination of Arrhenius rate constant for acidic hydrolysis of ethyl acetate at various temperatures. 4 C
- *Determination of the rate constant for the saponification reaction of ethyl acetate and sodium hydroxide. 4 C
- Determination of the void volume of a catalyst particle. 4 C
- *Determination of the solid density of a catalyst particle. 4 C
- Determination of the porosity of a catalyst particle. 4 C
- *Determination of order of reaction for saponification of ethyl-acetate with sodium hydroxide. 4 C
- Determination of the order of reaction for acidic hydrolysis of methyl acetate. 4 C
- *Determination of the kinetics of the reaction between ethyl acetate and sodium hydroxide in an isothermal batch reactor. 4 C
- Determination of the kinetics of saponification of ethyl acetate and sodium hydroxide in a Plug Flow Reactor. 4 C
- Determination of the kinetics of saponification of ethyl acetate and sodium hydroxide in a continuous stirrer tank reactor. 4 C
- Determination of rate constant by the half-life period of the saponification reaction between ethyl acetate and sodium hydroxide in an isothermal batch reactor. 4 C
- *Determination of kinetics of Bio-diesel synthesis from vegetable oils by Transesterification 4 C
- *The performance of three equal volumes of CSTR’s in series for the saponification of ethyl acetate and sodium hydroxide reactions. 4 C
Laboratory Equipment
- ISOTHERMAL BATCH REACTOR To determine the kinetic parameters affecting progress of a Chemicals reaction. Power 500 Watt (w), Voltage 240 Volt (v), Materials S S Metal Reactor of Capacity Min. 2 Ltrs fitted with Stirrer having Impeller and shaft coupled with DC Motor. Double walled Water Bath, insulated and fitted with agitator having Impeller and shaft coupledwith DC Motor with the help of bearings.Heater whose temperature controlled by PID Controller, 0-199.9degree C. Reactor, water bath, Impeller and shaft should be made of stainless steel .RPM of the stirrer should be displayed with the help of RPM sensor .Operating/instruction manual and sample calculations with Photographs, line diagram, detailed design and drawing of the impeller, must beprovided with equipment.Equipments has to be demonstrated at college site, results should be repeatable within plusminus5 to 10 % of the sample calculations provided. 1,2,3,4,5,9,10,11,
- ISOTHERMA PLUG FLOW REACTOR (PFR) To determine the Reaction Rate Constant and effect of temperature on saponification reaction in Isothermal Plug Flow Reactor. Helical Coiled Tube Type Reactor of min Volume 0.5Ltrs.Double walled Water Bath, insulated with Ceramic Wool and reactor fitted with stirrer having Impeller and shaft coupled with motor and Heater whose temperature controlled by PID Controller, 0-199.9degree C. Feed Circulation by pump and flow measurement device. Reactor, water bath, Impeller, shaft and feed tanks should be made of stainless steel Temperature measurement done by Temperature Sensors of RTD PT-100 type with Digital Temperature Indicator (0-199.9 degreeC). Operating/instruction manual consisting of experimental procedure, block diagram etc. and sample calculations should to be provided along with equipment.Equipments has to be demonstrated at college site, results should be repeatable within plusminus5 to 10% of the sample calculations provided. 12
- ISOTHERMAL CONTINUOS STIRRED TANK REACTOR To determine the Reaction Rate Constant and effect of temperature on Saponification Reaction in Isothermal CSTR. Reactor of min capacity 2 Ltrs fitted with agitation system and shaft coupled with Motor and min. four Baffles.Double walled Water Bath, insulated with Ceramic Wool should be fitted with Agitator having min 4 square bladed Impeller and shaft coupled with motor and Heater whose temperature controlled by PID Controller, 0-199.9degree C.Feed Circulation done by compressed air from Feed Tanks, 1.2 mm thick, capacity 20 liters each, made of stainless steel and Flow Measurement by Rotameter.Reactor, water bath, baffles, Impeller, shaft and feed tanks should be made of stainless steel and Piping of Stainless Steel and PU pipe. Bourdon type pressure gauge of 0-2 Kg/cm 2 and Pressure Regulator of 0-2 Kg/cm 2 should be provided. Temperature measurement done by Temperature Sensors of RTD PT-100 type with Digital Temperature Indicator (0-199.9 degreeC).Electricity Supply: Single Phase, 220 V AC, 50 Hz, 5-15 Amp combined socket with earth connection. Floor Drain. Laboratory Glassware and Chemicals required for analysis as per the system adopted. 13,16
Learning Materials
For the complete Syllabus, results, class timetable, and many other features kindly download the iStudy App
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Learning Websites
- https://onlinecourses.nptel.ac.in/noc19_ch20/preview Chemical Reaction Enginee
- https://nptel.ac.in/courses/103/103/103103153/ Chemical Reaction Enginee
- https://nptel.ac.in/courses/103/101/103101141/# Chemical Reaction Enginee
- https://onlinecourses.nptel.ac.in/noc19_ch20/preview Chemical Reaction Enginee
For detail Syllabus of all other subjects of Chemical Engineering, K scheme do visit Chemical Engineering 4th Sem Syllabus for K scheme.
For all Chemical Engineering results, visit MSBTE Chemical Engineering all semester results direct links.