2nd Sem, CH

2072: Engineering Chemistry Syllabus for Chemical Engineering 2nd Sem 2021 Revision SITTTR

Engineering Chemistry detailed syllabus for Chemical Engineering (CH) for 2021 revision curriculum has been taken from the SITTTRs official website and presented for the Chemical Engineering students. For course code, course name, number of credits for a course and other scheme related information, do visit full semester subjects post given below.

For Chemical Engineering 2nd Sem scheme and its subjects, do visit Chemical Engineering (CH) 2nd Sem 2021 revision scheme. The detailed syllabus of engineering chemistry is as follows.

Course Objectives:

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Course Outcomes:

On completion of the course, the student will be able to:

  1. Outline the basic concepts of inorganic and analytical chemistry
  2. Comprehend the fundamental concepts of organic chemistry to solve elementary problems in chemical engineering. 1
  3. Summarise the methods of preparation, chemical properties, reactions and uses of industrially important organic compounds. 1
  4. Apply chemical equilibria and kinetics of chemical reactions for the betterment of chemical engineering.

Module 1:

Periodicity in properties Statement of modern periodic law-explain the Moseley’s modern periodic table with emphasis to periods and groups-division of elements in to s, p, d and f block elements, explanation of periodicity of following physical properties along a period and down a group-atomic(covalent and Van der waals radii and ionic radius) .ionization energy, electron affinity and electronegativity. Analytical methods in Chemistry Oxidation, reduction and redox reactions, oxidation number, valency, variable valency, Qualitative analysis – solubility product, common ion effect, application of solubility product and common ion effect in the precipitation of cations during intergroup separation. Evaluation of analytical data, accuracy, precision, errors (absolute and relative error), methods of minimizing error (any three methods), methods of expressing precision- mean, median and standard deviation, simple problems for each.
Separation by chromatographic techniques Chromatography- theory- Types of chromatography -Adsorption and partition chromatography, Column chromatography and thin layer chromatography ,Partition chromatography-paper chromatography

Module 2:

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Module 3:

Preparation and important reactions of alkanes, alkenes, alkynes and organic compounds containing oxygen and nitrogen Preparation of hydrocarbons methane by decarboxylation of carboxylic acid using sodalime distillation-ethane by Wurtz reaction of chloromethane – ethene by dehydrohalogenation of chloroethane using alcoholic KOH – ethyne by action of water on calcium carbide and benzene by cyclic polymerization of ethynes. Chemical reactions of hydrocarbons – 1. chlorination of methane, ethane and ethyne, Benzene (substitution and addition reactions of chlorine under different conditions) 2. Addition reaction of Br2 in CCl4 to alkenes (test of unsaturation) – Addition of HBr to symmetrical and unsymmetrical alkenes – Markovnikov’s and AntiMarkovnikov’s addition 3. Acidity of ethyne – reaction with sodium and sodamide (test of alkynes) 4. methylation of benzene (Friedel – Craft’s reaction) Any three uses of methane, ethane, ethene, ethyne and benzene. Preparation of alcohols and phenol. ethanol – fermentation reaction and action of Grignard reagent on methanal – reaction of ethanol with ethanoic acid (esterification) – reaction of ethanol with chlorinating agents like Luca’s reagent , PCl3, PCl5 and SOCl2- oxidation reaction of ethanol using PCC and acidified K2Cr2O7 or KMnO4 – three uses of ethanol . Preparation of phenol – Dow’s process (from chlorobenzene) and Cumene process (from benzene)- electrophilic substitution reaction of phenol – bromination (Br2 in CS2 and Br2 in water) and nitration (dil.HNO3 and Conc.HNO3)- special reactions of phenol – Kolbe reaction and Reimer Tiemann reaction (no mechanism is required).
Preparation of aldehydes and ketones methanal from methanol – ethanal from ethanol – propanone from 2-methyl propan-2-ol, Nucleophilic addition of HCN to methanal and ethanal- Cannizaro’s reaction and aldol condensation reaction of methanal and ethanal – oxidation reactions of methanal, ethanal and propanone using strong oxidizing agents like alkaline or acidified KMnO4 and mild oxidizing agents like Tollen’s reagent and Fehling’s solution (test of aldehydes and ketones). Structure of glucose – open chain and ring structure- chemical reactions of glucose -reduction using HI, oxidation using Br2 in water and HNO3 – acetylation using acetic anhydride and osazone formation using phenyl hydrazine Preparation of carboxylic acid Method of preparation of ethanoic acid from CO2 using Grignard reagent – chemical properties – reduction reaction and HVZ reaction of ethanoic acid . Preparation of symmetrical and unsymmetrical ethers – Williamson’s synthesis (preparation diethyl ether and ethyl methyl ether), formation of epoxides ( formation of epoxy ethane from ethylene any three uses of ether. Preparation of amines
Preparation of aniline- by reduction of nitrobenzene- diazotization of aniline – formation of benzene diazonium chloride – conversion of benzene diazonium chloride to phenol , chlorobenzene (Sandmeyer’s reaction and Gattermann reaction ) and benzene.
Amino acid -classification of amino acids- essential and nonessential amino acids with two examples each essential amino acids -valine and leucine, nonessential amino acids – glycine and alanine (structures are required) – preparation of glycine by Strecker’s synthesis, properties of alpha amino acids- zwitterion structure – definition and significance of isoelectric point – formation of peptide bond and proteins – test of proteins – biuret test ,xanthoproteic and ninhydrin test (no chemistry is required)

Module 4:

Chemical Equilibrium: Reversible and Irreversible reactions with two examples for each-Statement of Law of mass action-Equilibrium constants-Equilibrium concentration of reactants and products molar concentration and partial pressure-Derivation of expressions for equilibrium constants-Kc and Kp-Law of chemical equilibrium-Derivation of relation between Kc and Kp-Application of the relation to three chemical equilibria H2 + I2 >2HI, N2 + 3H2 > 2NH3 and N2O4 2NO2 and simple problems using this relation Lechateleir’s principle-Statement and application of Le – Chateleir’s principle to synthesis of ammonia by Haber process and manufacture of sulphuric acid by contact process. Chemical Kinetics Rate of chemical reaction- definition and unit-Factors affecting rate of chemical reaction -rate law and rate constant-order and molecularity -examples of first order, second order and third order reactions examples of Unimolecular,bimolecular and trimolecular reactions-Difference between order and molecularity of reaction- Derivation of an expression of rate constant of first order reactions-Definition of half life period and derivation of expression of half life period from expression of first order rate constant problems using these expressions-Effect of temperature on reaction rate-Definition of Threshold energy and Activation energy- Arrhenius equation- Exponential forms and logarithmic forms- Explanation of terms- Arrhenius frequency factor and activation energy.

Text Books:

For the complete syllabus, results, class timetable, and many other features kindly download the iStudy App
It is a lightweight, easy to use, no images, and no pdfs platform to make students’s lives easier.
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Reference Books:

  1. Engineering Chemistry; P.C.Jain & MonikaJain
  2. Textbook of physical Chemistry; P.L.Soni,O.P.Dharmatha
  3. Textbook of physical Chemistry; Samuel Glasstone
  4. Elements of Physical Chemistry; Glasstone &Lewis

Online Resources

For the complete syllabus, results, class timetable, and many other features kindly download the iStudy App
It is a lightweight, easy to use, no images, and no pdfs platform to make students’s lives easier.
Get it on Google Play.

For detailed syllabus of all other subjects of Chemical Engineering (CH), 2021 revision curriculum do visit Chemical Engineering 2nd Sem subject syllabuses for 2021 revision.

To see the syllabus of all other branches of diploma 2021 revision curriculum do visit SITTTR diploma all branches syllabus..

To see the results of Chemical Engineering (CH) of diploma 2021 revision curriculum do visit SITTTR diploma Chemical Engineering (CH) results..

For all Chemical Engineering academic calendars, visit Chemical Engineering all semesters academic calendar direct link.

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