Syllabus

JNTUK B.Tech Organic Chemistry for R13 Batch.

JNTUK B.Tech Organic Chemistry gives you detail information of Organic Chemistry R13 syllabus It will be help full to understand you complete curriculum of the year.

Learning Objectives
The students will be imparted the knowledge of

  • organic reactants, intermediates and their stability- effect of intermediates and steric inhibition on reaction rates and mechanism of the reaction.
  • the step wise mechanism of reactions – different intermediates formed in the reactions – the reaction path way in the formation of products.
  • reactions which are proceeding through free radical mechanism-effect of heat and light on these chemical reactions.
  • the static and dynamic aspects of the three-dimensional shapes of molecules-a foundation for understanding structure and reactivity.
  • coal-its constituents – aromatic compounds and their extraction methods – is important.
  • synthesis and reactivity of heterocyclics- the recent trends in application of heterocyclic compounds in advanced chemical synthesis.
  • the functional groups which that impart colour to the compounds-preparation and uses of these compounds.

UNIT-I : Polar effects – Inductive effect, Electromeric effect, Resonance, Hyper conjugation, Steric Inhibition of resonance – Examples.

UNIT-II : Mechanism and application of following organic reactions: a) Friedel-Craft reaction b) Riemer- Teimenn Reaction c) Beckmann rearrangement d) Aldol condensation e) Perkin Reaction f)
Benzoin condensation.

UNIT-III : a) Halogenation of Alkane b) Addition of HBr to Alkene in the presence of peroxide c) Allylic halogenation using N-Bromo succinimide (NBS) d) Thermal halogenation of Alkanes.

UNIT-IV : Stereo isomerism; Optical isomerism; Symmetry and chirality; Optical isomerism in lactic acid and tartaric acid; Sequence rules; Enantiomers, Geometrical Isomerism; E-Z system of nomenclature, conformational analysis of ethane and cyclohexane.

UNIT-V : Sources of aromatic compounds: Aromatics from coal, carbonization of coal, coal gas manufacture and recovery of aromatics, fractional distillation of coal tar, methods of preparation of aromatics from petroleum products (catalytic reforming, high temperature cracking etc.,).

UNIT-VI : Heterocyclic compounds: Nomenclature, preparation, properties and uses of (1) Pyrrole (2) Furan (3) Thiophene (4) Pyridine (5) Quinoline (6) Iso-quinoline. Dyes – Colour and Constituion; Classification of Dyes; Preparation and uses of (1) Malachite green (2) Rosaniline (3) Congored (4) Bismark brown (5) Fluoroscien.

Outcomes:  After successful completion of the course, the students will

  • have a basic knowledge of the factors that influence the stability and the reactivity of organic substances.
  • be able to conduct a chemical reaction whether it is on lab scale or industrial scale with comlete understanding of its mechanism.
  • be able to understand reactions taking place via free radical mechanism particularly in petroleum refining processes
  • have knowledge of isomerism, particularly stereoisomerism and the complexity of organic molecules.
  • have knowledge of aromatic compounds which are precursors for a number of industrial organic products like drugs, dyes etc.

Text Books

  • Morrison, R. T., R. N. Boyd and Saibal, Kranti Bhattacharjee, Organic Chemistry, Pearson, 2011.
  • L. N. Ferguson, The Text of Organic Chemistry, 2nd Edition, East-West Press, 2009.

Reference Books

  • Finar, I. L., Organic Chemistry, Vol 1, Pearsons, 2002.
  • Peter Sykes, A Guidebook to Mechanism in Organic Chemistry, 6th Edition, Pearson, 2003.
  • Bansal, R. K., A Textbook of Organic Chemistry, 5th Edition, New Age International, 2007.
  • Agarwal, O. P., Organic Chemistry Reactions and Reagents, 47th Edition, Krishna Prakashan Media (P) Ltd., 2011.
  • Arun Bahl and B. S. Bahl, Advanced Organic Chemistry, S. Chand Publishers, 2010.
  • H. M. Chawla and P. L. Soni, Textbook of Organic Chemistry, Sultan Chand & Sons, 2012.

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