JNTUK B.Tech Chemical Engineering Thermodynamics –II gives you detail information of Chemical Engineering Thermodynamics –II R13 syllabus It will be help full to understand you complete curriculum of the year.
Learning Objectives
The student will be able to learn:
- Sensible heat effects and latent heat
- Heat effects of industrial reactions.
- Heat effects for chemical change.
- Estimation of properties of solutions.
- Concept of fugacity and partial molar properties.
- VLE calculations using Raoult’s law, modified Raoult’s law and generalized method.
- VLE calculations from equation of state.
- Estimation of reaction equilibrium constant and equilibrium conversion for liquid phase reactions, gas phase reactions and industrial reactions.
- Applications of phase rule for reacting and non-reacting systems.
UNIT –I: Heat effects: Sensible heat effects, Internal energy of ideal gases: Microscopic view, Latent heats of pure substances, heat effects of industrial reactions, heat effects of mixing processes. Standard heat of reaction, Standard heat of formation, Standard heat of combustion, temperature dependence of heat of reaction.
UNIT-II: Solution thermodynamics: Theory: Fundamental property relation, Petrochemical potential as a criterion for phase equilibrium, partial properties, ideal gas mixtures, fugacity and fugacity coefficient for pure species, fugacity and fugacity coefficient for species in solutions, generalized correlations for Fugacity coefficient, The ideal solutions, excess properties.
UNIT-III: Solution thermodynamics: applications: the liquid phase properties from VLE data, models for the excess Gibbs energy, property changes of mixing
UNIT–IV: VLE at low to moderate pressures: The nature of equilibrium, the phase rule, Duhems theorem, VLE: Qualitative behavior, the gamma /Phi formulation of VLE, Dew point and bubble point calculations, flash calculations, solute (1)/solvent (2) systems
UNIT–V: Thermodynamic properties and VLE from equations of state: properties of fluids from the virial equations of state, properties of fluids from cubic equations of state, fluid properties from correlations of the Pitzer type, VLE from cubic equations of state.
UNIT–VI: Chemical Reaction Equilibria: The reaction coordinate, application equilibrium criterion to Petrochemical reactions, the standard Gibb’s energy change and the equilibrium constant, effect of temperature on equilibrium constants, relation of equilibrium constants to composition, equilibrium conversion for single reactions, Phase rule and Duhem’s theorem for reacting systems.
Outcomes
After the completion of course, students will be able to
- Estimate heat requirement for any physical change and chemical change.
- Find fugacity coefficient and activity coefficient for a component in a mixture.
- Identify the non-ideal solution model for vapour liquid equilibrium.
- Obtain VLE data using appropriate cubic equations of state.
- Apply phase rule.
- Find reaction equilibrium constant and equilibrium conversion for single reactions and multiple reactions.
Text Books
- Introduction to Chemical Engineering Thermodynamics, J.M. Smith, H.C. Van Ness and M.M. Abbott, 7th ed. McGraw Hill, 2005.
- Chemical Engineering Thermodynamics, Rao Y.V.C., Universities Press (India) Pvt. Ltd., 1997.
Reference Books
- Chemical and Process Thermodynamics, BG Kyle, 3rd Edition, Phi Learning, 2008.
- Introductory Chemical Engineering Thermodynamics, J. Richard Elliott, Carl T. Lira, 2nd Edition, Prentice Hall, 2012.
- Chemical, Biochemical and Engineering Thermodynamics, Stanley I Sandler, 4th Edition, Wiley India Pvt Ltd, 2006.
- Molecular Thermodynamics In Fluid Phase Equilibria, J.M. Prausnitz, R.N. Lichtenthaler, E.G.de Azvedo, 3rd Edition, Prentice-Hall, 1998.
- Engineering and Chemical Thermodynamics, Milo D. Koretsky, Wiley India Pvt Ltd, 2009
- Thermodynamics: Applications in Chemical Engineering and the Petroleum Industry, J. Vidal, Editions Technip, 2003.
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